4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl, purum, >=98.0% (HPLC)

Code: 00375-1G D2-231

Application

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be emplo...


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Application

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

General description

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.

Other Notes

New oxidant for the mild oxidation of alcohols to carbonyls

assay≥98.0% (HPLC)
gradepurum
greener alternative categoryRe-engineered
greener alternative product characteristicsWaste PreventionSafer Solvents and AuxiliariesInherently Safer Chemistry for Accident PreventionLearn more about the Principles of Green Chemistry.
greener alternative product scoreold score: 9new score: 8Find out more about DOZN™ Scoring
InChI keyUXBLSWOMIHTQPH-UHFFFAOYSA-N
InChI1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
mp143-145 °C (lit.), 143-146 °C
Quality Level200
SMILES stringCC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
storage temp.2-8°C
Cas Number14691-89-5
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