4-(Trifluoromethyl)benzenesulfonyl chloride, 97%

Code: 565849-1G D2-231

Application

4-(Trifluoromethyl)benzenesulfonyl chloride may be used to synthesize β-arylated thiophenes and 2,5-diarylated pyrrolevia palladium catalyzed desulfitative arylat...


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Your Price
€29.80 1G
€36.65 inc. VAT

Application

4-(Trifluoromethyl)benzenesulfonyl chloride may be used to synthesize β-arylated thiophenes and 2,5-diarylated pyrrolevia palladium catalyzed desulfitative arylation of thiophenes and pyrroles, respectively.4-(Trifluoromethyl)benzenesulfonyl chloride and N-vinylpyrrolidinone in acetonitrile can undergo photo-irradiation with visible light in the presence of Ir(ppy)2(dtbbpy)PF6 ([4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III)hexafluorophosphate) and disodium phosphate to give the corresponding E-vinyl sulfone.

Caution

Low Melting Solid

Packaging

1, 5 g in glass bottle

assay97%
InChI keyOZDCZHDOIBUGAJ-UHFFFAOYSA-N
InChI1S/C7H4ClF3O2S/c8-14(12,13)6-3-1-5(2-4-6)7(9,10)11/h1-4H
mp30-34 °C (lit.)
Quality Level100
SMILES stringFC(F)(F)c1ccc(cc1)S(Cl)(=O)=O
Cas Number2991-42-6
Hazard Class8
Un Number3261
Pack GroupII
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