Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II),

Code: 667234-250MG D2-231

Application

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.It can b...


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Your Price
€187.00 250MG
€230.01 inc. VAT

Application

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.It can be used: To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.To catalyze C-C coupling of norbornenes and norbornadiene with alkynesto form [2 + 2] cycloadducts.In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

Packaging

1 g in glass bottle

250 mg in glass bottle

InChI keyMQMQNIQJGNBEMG-ONEVTFJLSA-M
InChI1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;;
mp143-147 °C
Quality Level100
reaction suitabilitycore: ruthenium, reagent type: catalyst
SMILES stringCl[Ru].C1CC=CCCC=C1.C[C]2[C](C)[C](C)[C](C)[C]2C
storage temp.−20°C
Cas Number92390-26-6
Hazard Class4.3
Un Number3395
Pack GroupII
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