2,6-Di-tert-butyl-4-methylpyridine, 98%

Code: 249505-25G D2-231

Application

2,6-Di-tert-butyl-4-methylpyridine has been used:in the synthesis of 1,2-dihydro-2-silanaphthalene derivativesas base in PtCl4-catalyzed cycli...


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Your Price
€500.00 25G
€615.00 inc. VAT

Application

2,6-Di-tert-butyl-4-methylpyridine has been used:in the synthesis of 1,2-dihydro-2-silanaphthalene derivativesas base in PtCl4-catalyzed cyclization reactions of homopropargyl azide derivativesdiastereoselective synthesis of β-thiomannopyranosides

General description

2,6-Di-tert-butyl-4-methylpyridine is a sterically hindered, non-nucleophilic base which distinguishes between BrÖnsted (protonic) and Lewis acids. It also enables the direct high-yield conversion of aldehydes and ketones to vinyl triflates. It inhibits desilylation and hydration of the products during GaCl3-catalyzed ortho-ethynylation of phenol.

Packaging

1, 5, 25 g in glass bottle

assay98%
bp233 °C (lit.)
formsolid
InChI keyHVHZEKKZMFRULH-UHFFFAOYSA-N
InChI1S/C14H23N/c1-10-8-11(13(2,3)4)15-12(9-10)14(5,6)7/h8-9H,1-7H3
mp33-36 °C (lit.)
Quality Level200
refractive indexn20/D 1.4763 (lit.)
SMILES stringCc1cc(nc(c1)C(C)(C)C)C(C)(C)C
solubilityethanol: soluble 5%, clear to slightly hazy, colorless to dark yellow
storage temp.2-8°C
Cas Number38222-83-2
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