638021-5G Display Image

DavePhos, 97%

Code: 638021-5G D2-231

Application

DavePhos may be used as a ligand in the following reactions:Palladium catalyzed sp3 arylation of 2-substituted-N-iminopyridinium ylid...


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Your Price
€335.00 5G
€412.05 inc. VAT

Application

DavePhos may be used as a ligand in the following reactions:Palladium catalyzed sp3 arylation of 2-substituted-N-iminopyridinium ylides with different aryl chlorides to yield functionalized pyridines.Preparation of functionalized benzylic sulfones via palladium-catalyzed Negishi cross-coupling between alkyl sulfones and aryl halides.C-C Coupling of 3-haloquinolines with aryl sulfinates via palladium-catalyzed desulfitative arylation to form the corresponding biaryl compounds.

Ligand used in a Pd-catalyzed Suzuki aryl-aryl coupling leading to benzodioxepines.

Useful ligand for Pd-catalyzed C-N bond formation; amination of aryl halides containing hydroxyl, amide, or enolizable ketones.

Legal Information

Usage subject to US Patents 6307087 and 6395916.

Packaging

1, 5, 25, 100 g in glass bottle

assay97%
functional groupphosphine
InChI keyZEMZPXWZVTUONV-UHFFFAOYSA-N
InChI1S/C26H36NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h9-12,17-22H,3-8,13-16H2,1-2H3
mp121-124 °C (lit.)
Quality Level200
reaction suitabilityreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reagent type: ligandreaction type: Hydroaminations, reagent type: ligandreaction type: Arylations, reagent type: ligandreaction type: Negishi Coupling, reagent type: ligandreaction type: Suzuki-Miyaura Coupling, reagent type: ligandreaction type: Kumada Coupling
SMILES stringCN(C)c1ccccc1-c2ccccc2P(C3CCCCC3)C4CCCCC4
Code
Description
Unit Size
List Price
Qty
638021-1G
Unit:1G
List Price: €77.00
Source:List Price
ADD
638021-25G
Unit:25G
List Price: €1,510.00
Source:List Price
ADD
Cas Number213697-53-1
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