AdBrettPhos Pd G3

Code: 776106-100MG D2-231

Application

Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying ap...


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€90.00 100MG
€110.70 inc. VAT
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Application

Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates.Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts

Packaging

2, 5 g in glass bottle

100, 500 mg in glass bottle

featuregeneration 3
formsolid
functional groupphosphine
InChI keyOZFYYHNERORONM-UHFFFAOYSA-M
InChI1S/C43H61O2P.C12H10N.CH4O3S.Pd/c1-25(2)34-17-35(26(3)4)39(36(18-34)27(5)6)40-37(44-7)9-10-38(45-8)41(40)46(42-19-28-11-29(20-42)13-30(12-28)21-42)43-22-31-14-32(23-43)16-33(15-31)24-43;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-10,17-18,25-33H,11-16,19-24H2,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
mp251-253 °C
Quality Level100
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalystreaction type: Cross Couplings
SMILES stringCOC1=CC=C(OC)C(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=C1P([C@]34C[C@H]5C[C@H](C[C@H](C5)C4)C3)[C@@]6(C[C@H](C7)C8)CC7C[C@H]8C6.NC9=CC=CC=C9C=CC=CC=C[Pd]OS(C)(=O)=O
Code
Description
Unit Size
List Price
Qty
776106-2G
AdBrettPhos Pd G3

Unit:2G
List Price: €883.00
Source:List Price
ADD
776106-500MG
AdBrettPhos Pd G3

Unit:500MG
List Price: €307.00
Source:List Price
ADD
776106-5G
DI-AD-BRETTPHOS-G3-PALLADACYCLE

Unit:5G
List Price: €2,110.00
Source:List Price
ADD
Cas Number1445972-29-1
This product has met the following criteria: