XPhos Pd G2,

Code: 741825-1G D2-231

Application

XPhos Pd G2 was employed as catalyst in the following reactions:Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulf...


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Application

XPhos Pd G2 was employed as catalyst in the following reactions:Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulfamates. Suzuki-Miyaura cross-coupling reactions of sensitive aryl and heteroarylboronic acids.Synthesis of potassium Boc-protected secondary aminomethyltrifluoroborates, via Suzuki-Miyaura cross-coupling reaction.

2nd Generation Buchwald Precatalysts Widely used for Suzuki-Miyaura cross-coupling reactions

General description

XPhos Pd G2 is a bulky monodentate biaryl ligand. It is a Buchwald′s 2nd generation preformed catalyst. It undergoes rapid reductive elimination to form a reactive, monoligated Pd(0) species.

Packaging

1, 5, 10, 25, 100, 500 g in glass bottle

250 mg in glass bottle

assay98%
featuregeneration 2
formsolid
functional groupphosphine
InChI keyHMRJFNBZAWHTGN-UHFFFAOYSA-L
InChI1S/2C33H49P.2C12H10N.2ClH.2Pd/c1-23(2)27-21-31(24(3)4)33(32(22-27)25(5)6)26-14-13-19-30(20-26)34(28-15-9-7-10-16-28)29-17-11-8-12-18-29;1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;2*13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;;;/h13-14,19-25,28-29H,7-12,15-18H2,1-6H3;13-14,19-25,27-28H,7-12,15-18H2,1-6H3;2*1-6,8-9H,13H2;2*1H;;/q;;;;;;2*+1/p-2
mp202-210 °C
Quality Level100
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalystreaction type: Cross Couplings
SMILES stringNc1ccccc1-c2ccccc2[Pd]Cl.Nc3ccccc3-c4ccccc4[Pd]Cl.CC(C)c5cc(C(C)C)c(-c6cccc(c6)P(C7CCCCC7)C8CCCCC8)c(c5)C(C)C.CC(C)c9cc(C(C)C)c(c(c9)C(C)C)-ccccccP(CCCCCC)CCCCCC
Cas Number1310584-14-5
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