Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II), 98%

Code: 660361-250MG D2-231

Application

Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary...


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€123.00 250MG
€151.29 inc. VAT
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Application

Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.

General description

Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) is an air-stable, well-defined palladium N-heterocyclic carbene complex, which can efficiently catalyze A-arylation of ketones.

Legal Information

Product of Umicore Additional information available at www.pmc.umicore.com

Packaging

1 g in glass bottle

250 mg in glass bottle

assay98%
InChI keyYVIDBHQABBIAAW-UHFFFAOYSA-M
InChI1S/C27H37N2.C3H5.ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-3-2;;/h9-21H,1-8H3;3H,1-2H2;1H;/q;;;+1/p-1
mp>300 °C
Quality Level100
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalyst
SMILES string[CH2][CH][CH2].CC(C)c1cccc(C(C)C)c1N2C=CN(C2[Pd]Cl)c3c(cccc3C(C)C)C(C)C
Cas Number478980-03-9
This product has met the following criteria to qualify for the following awards:



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