Pentamethylcyclopentadienylrhodium(III) chloride dimer,

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for: Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp² C-H bond Amidation reactions Reductive alkylation reactions

Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for: The synthesis of multiaryl substituted naphthols via dual C-H bond functionalization of 2-aryloxypyridines. Regioselective C-N bond formation of azo compounds, wherein azide acts as a nitrogen source. Annulation of N-benzoylsulfonamide with isocyanide via C-H bond activation.

Legal Information

Product of UmicoreAdditional information available at www.pmc.umicore.com

Packaging

500 mg in glass bottle

2 g in glass bottle