RuCl(p-cymene)[(S,S)-Ts-DPEN],

Code: 703915-100MG D2-231

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst involved in: Asymmetric transfer hydrogenation of imines and ketones Intramolecular asymmet...


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€45.30 100MG
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Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst involved in: Asymmetric transfer hydrogenation of imines and ketones Intramolecular asymmetric reductive amination Tandem hydroformylation / hydrogenation of terminal olefinsReactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

General description

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.

Legal Information

Sold in collaboration with Takasago for research purposes only. WO9720789

Packaging

100 mg in clear glass bottle

500 mg in amber glass bottle

formsolid
InChI keyAZFNGPAYDKGCRB-XCPIVNJJSA-M
InChI1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
mp>175 °C
optical activity[α]20/D +178°, c = 0.5 in chloroform
Quality Level100
SMILES stringCC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
storage temp.2-8°C
Cas Number192139-90-5
This product has met the following criteria to qualify for the following awards:



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