RuCl(p-cymene)[(R,R)-Ts-DPEN],

Code: 703907-500MG D2-231

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:•Quinolines&b...


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€103.00 500MG
€126.69 inc. VAT
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Application

Takasago Ligands and Complexes for Asymmetric Reactions

Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:•Quinolines•N-Alkyl ketimines•Antitumor and antiproliferative derivatives of natural products isolated from bacteria•Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenationCatalyst with improved performance modified via microenvironment engineering of nanocages

General description

RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium.

Legal Information

Sold in collaboration with Takasago for research purposes only. WO9720789

Packaging

100 mg in clear glass bottle

500 mg in amber glass bottle

formpowder
InChI keyAZFNGPAYDKGCRB-AGEKDOICSA-M
InChI1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
mp215 °C
optical activity[α]20/D −116°, c = 0.1 in chloroform
Quality Level100
SMILES stringCC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
storage temp.2-8°C
Cas Number192139-92-7
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