(S)-DTBM-SEGPHOS, >=94%

Code: 692980-1G D2-231

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalytic ligand for: Enantioselective synthesis of secondary allylic alcohols via enantioselective ...


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Your Price
€189.50 1G
€233.09 inc. VAT

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalytic ligand for: Enantioselective synthesis of secondary allylic alcohols via enantioselective reductions of α,β-unsaturated ketones Stereoselective preparation of cyclohexanone derivatives via rhodium-catalyzed rearrangement of allyl or allenic cyclobutanols Cu-catalyzed asymmetric conjugate reduction of beta-substituted unsaturated phosphonates to give optically active beta-stereogenic alkylphosphonates Asymmetric synthesis of cyclohexenones via Rh-catalyzed desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols Enantioselective synthesis and crystal structure of P-stereogenic alkynylphosphine oxides by Rh-catalyzed [2+2+2] cycloaddition

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Packaging

1 g in glass bottle

50, 100 mg in glass insert

assay≥94%
formpowder
InChI keyZNORAFJUESSLTM-UHFFFAOYSA-N
InChI1S/C74H100O8P2/c1-67(2,3)47-33-43(34-48(61(47)75-25)68(4,5)6)83(44-35-49(69(7,8)9)62(76-26)50(36-44)70(10,11)12)57-31-29-55-65(81-41-79-55)59(57)60-58(32-30-56-66(60)82-42-80-56)84(45-37-51(71(13,14)15)63(77-27)52(38-45)72(16,17)18)46-39-53(73(19,20)21)64(78-28)54(40-46)74(22,23)24/h29-40H,41-42H2,1-28H3
Quality Level100
SMILES stringCOc1c(cc(cc1C(C)(C)C)P(c2cc(c(OC)c(c2)C(C)(C)C)C(C)(C)C)c3ccc4OCOc4c3-c5c6OCOc6ccc5P(c7cc(c(OC)c(c7)C(C)(C)C)C(C)(C)C)c8cc(c(OC)c(c8)C(C)(C)C)C(C)(C)C)C(C)(C)C
Cas Number210169-40-7
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