Ethyl acetoacetate, ReagentPlus, 99%

Code: 537349-1KG D2-231

Application

Ethyl acetoacetate is a versatile reagent that can be used as a nucleophile in alkylation, conjugate addition and condensation reactions. Some of its applications...


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€73.80 1KG
€90.77 inc. VAT

Application

Ethyl acetoacetate is a versatile reagent that can be used as a nucleophile in alkylation, conjugate addition and condensation reactions. Some of its applications are:Alkylation at the α-carbon of ethyl acetoacetate followed by hydrolysis and decarboxylation can afford a variety of methyl ketones. It also undergoes acylation at the α-carbon in the presence of MgCl2 and pyridine to give synthetically important intermediates.It can be used in Knoevenagel condensation with aliphatic, aromatic, and heteroaromatic aldehydes to produce α-alkylideneacetoacetates.

Legal Information

ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Packaging

1, 3 kg in poly bottle

assay99%
autoignition temp.580 °F
bp181 °C (lit.)
density1.029 g/mL at 20 °C (lit.)
expl. lim.9.5 %
InChI keyXYIBRDXRRQCHLP-UHFFFAOYSA-N
InChI1S/C6H10O3/c1-3-9-6(8)4-5(2)7/h3-4H2,1-2H3
mp−43 °C (lit.)
product lineReagentPlus®
Quality Level200
SMILES stringCCOC(=O)CC(C)=O
solubilitywater: soluble 130 g/L at 20 °C
vapor density4.48 (vs air)
vapor pressure1 mmHg ( 28.5 °C)
Cas Number141-97-9
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