(tert-Butyldimethylsilyloxy)acetaldehyde, 90%

Code: 449458-1G D2-231

Application

(tert-Butyldimethylsilyloxy)acetaldehyde is a versatile reagent commonly used in synthetic glycobiology. It can act both as an aldol donor and an aldol a...


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€107.00 1G
€131.61 inc. VAT

Application

(tert-Butyldimethylsilyloxy)acetaldehyde is a versatile reagent commonly used in synthetic glycobiology. It can act both as an aldol donor and an aldol acceptor in the stereocontrolled production of erythrose. It is used as an important reagent in the total synthesis of (+)-ambruticin, (−)-laulimalide, (−)-salinosporamide A, and (+)-leucascandrolide A.

Employed in the construction of the key tetrahydropyran subunit in a recent synthesis of the marine natural product (–)-dactylodide.

Packaging

1, 5 g in glass bottle

assay90%
bp165-167 °C (lit.)
density0.915 g/mL at 25 °C (lit.)
InChI keyMEBFFOKESLAUSJ-UHFFFAOYSA-N
InChI1S/C8H18O2Si/c1-8(2,3)11(4,5)10-7-6-9/h6H,7H2,1-5H3
refractive indexn20/D 1.432 (lit.)
SMILES stringCC(C)(C)[Si](C)(C)OCC=O
storage temp.2-8°C
Cas Number102191-92-4
Hazard Class3
Un Number1989
Pack GroupIII
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