Diethyl chloromalonate, 95%

Code: 437786-5ML D2-231

General description

Diethyl chloromalonate (Diethyl α-chloromalonate) is a 2-halo-1,3-dicarbonyl compound. It participates in K2CO3-catalyzed domino rea...


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General description

Diethyl chloromalonate (Diethyl α-chloromalonate) is a 2-halo-1,3-dicarbonyl compound. It participates in K2CO3-catalyzed domino reactions (Michael alkylation, Mannich alkylation, and aldol alkylation) of salicylic aldehyde derivatives to afford functionalized 2,3-dihydrobenzofurans. It reacts with Cs2CO3 in the presence of elemental S8 or Sen to afford the corresponding diethyl thioxo- or selenoxomalonates, which can be trapped in situ with various 1,3-dienes.

Packaging

5, 25 mL in glass bottle

assay95%
density1.204 g/mL at 25 °C (lit.)
formliquid
InChI keyWLWCQKMQYZFTDR-UHFFFAOYSA-N
InChI1S/C7H11ClO4/c1-3-11-6(9)5(8)7(10)12-4-2/h5H,3-4H2,1-2H3
Quality Level100
refractive indexn20/D 1.432 (lit.)
SMILES stringCCOC(=O)C(Cl)C(=O)OCC
Cas Number14064-10-9
Hazard Class8
Un Number3265
Pack GroupII
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