Ethyl potassium malonate, 98%

Code: 360899-25G D2-231

Application

Ethyl potassium malonate (potassium ethyl malonate) may be used to generate (trimethylsilyl)ethyl malonate in situ, which can be acylated to prepare a va...


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€58.90 25G
€72.45 inc. VAT
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Application

Ethyl potassium malonate (potassium ethyl malonate) may be used to generate (trimethylsilyl)ethyl malonate in situ, which can be acylated to prepare a variety of β-ketoesters or alkylidene malonates.

General description

Ethyl potassium malonate (potassium ethyl malonate) reacts with aryl nitriles in the presence of zinc chloride and a catalytic amount of Hünig′s base to yield β-amino acrylates. Ethyl potassium malonate is formed as an intermediate during the synthesis of ethyl tert-butyl malonate.

Packaging

25, 100 g in poly bottle

assay98%
formsolid
InChI keyWVUCPRGADMCTBN-UHFFFAOYSA-M
InChI1S/C5H8O4.K/c1-2-9-5(8)3-4(6)7;/h2-3H2,1H3,(H,6,7);/q;+1/p-1
mp194 °C (dec.) (lit.)
Quality Level200
SMILES string[K+].CCOC(=O)CC([O-])=O
Cas Number6148-64-7
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