Dimethyl bromomalonate, technical grade, 90%

Code: 359890-5ML D2-231

Application

Dimethyl bromomalonate may be used in the enantioselective synthesis of nitrocyclopropanes.

General description

Dimethyl bromomalonat...


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Your Price
€56.10 5ML
€69.00 inc. VAT

Application

Dimethyl bromomalonate may be used in the enantioselective synthesis of nitrocyclopropanes.

General description

Dimethyl bromomalonate undergoes manganese(III)-promoted free-radical chain addition reaction with olefins, to yield dimethyl 2-bromoalkylmalonates. Organocatalyzed Michael addition of dimethyl bromomalonate to nitrostyrenes to yield synthetically useful nitrocyclopropanes has been reported. Dimethyl bromomalonate reacts readily with arylnitroso compounds to yield the corresponding N-aryl-C,C-dimethoxycarbonylnitrones.

Packaging

5, 25 mL in glass bottle

assay90%
bp105-108 °C/11 mmHg (lit.)
density1.601 g/mL at 25 °C (lit.)
formliquid
gradetechnical grade
InChI keyNEMOJKROKMMQBQ-UHFFFAOYSA-N
InChI1S/C5H7BrO4/c1-9-4(7)3(6)5(8)10-2/h3H,1-2H3
Quality Level100
refractive indexn20/D 1.460 (lit.)
SMILES stringCOC(=O)C(Br)C(=O)OC
Cas Number868-26-8
Hazard Class8
Un Number3265
Pack GroupII
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