Analysis Note
Assay (iodometric): 23.0 - 26.0 Þnsity (d 20 °C/ 4 °C): 1.200 - 1.220
Application
Sodium chlorite (NaClO2) can be used as an oxidizing agent for the conversion of: Aldehydes to corresponding carboxylic acids under mild reaction conditions in the presence of scavengers such as sulfamic acid or resorcinol.Primary alcohols to carboxylic acids in the presence of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and NaOCl. Aliphatic and aromatic thiols to the corresponding disulfides.Aryl boronic acids to phenols via ipso-hydroxylation.Cyclic benzylic ethers and N-protected cyclic benzylic amines to benzolactones and benzolactams.Alkenes to epoxides using aldehydes as promoters. Alkenes and cycloalkenes to 1, 2 diols via osmium-catalyzed Sharpless asymmetric dihydroxylation. It can also be used in combination with Br2 to synthesize 2-carboxyazetidin-2-ones from furanylazetidinones.
Packaging
1 l in Glass bottle
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