trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 95%

Code: 212830-5G D2-231

Application

trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene was used:in the synthesis of sulfone analogues of griseofulvin (sulfogriseofulvins), 4H-1-aminop...


read more

Your Price
€192.00 5G
€236.16 inc. VAT
REQUEST

Application

trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene was used:in the synthesis of sulfone analogues of griseofulvin (sulfogriseofulvins), 4H-1-aminopyrroles and 4,5H-pyrazolesas Diels-Alder diene for the synthesis of pyridones and pyranones as reagent employed in the Mannich-Michael reaction for preparation of piperidinones and enaminones

General description

trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene is a funtionalized Diels-Alder diene. Mukaiyama-Michael-type addition/heterocyclization of trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene (Danishefsky′s diene) with 1,2-diaza-1,3-butadiene has been investigated. Asymmetric hetero-Diels-Alder cyclization of Danishefsky′s diene with benzaldehyde catalyzed by mesoporous inorganic/metalorganic hybrid materials has been reported.

Packaging

1, 5 g in ampule

assay95%
bp68-69 °C/14 mmHg (lit.)
density0.885 g/mL at 25 °C (lit.)
formliquid
impurities2-5% 4-methoxy-3-buten-2-one
InChI keySHALBPKEGDBVKK-VOTSOKGWSA-N
InChI1S/C8H16O2Si/c1-8(6-7-9-2)10-11(3,4)5/h6-7H,1H2,2-5H3/b7-6+
Quality Level100
refractive indexn20/D 1.454 (lit.)
SMILES stringCOC=CC(=C)O[Si](C)(C)C
storage temp.2-8°C
Cas Number54125-02-9
Hazard Class3
Un Number1993
Pack GroupIII
This product has met the following criteria to qualify for the following awards:



PROCEED TO CHECKOUT

HAVE AN ACCOUNT? LOGIN

GUEST CHECKOUT

Proceed as a guest. You will have the option to register to access exclusive pricing and stock availability features after checkout.