Proton-sponge, 99%

Code: 158496-10G D2-231

Application

Proton-sponge can be used in the synthesis of C-substituted t-BuNH-8,9-R,R′-nido-7,8,9-C3B8H9 (R,R′ = H,H; MeH;...


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€53.10 10G
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Application

Proton-sponge can be used in the synthesis of C-substituted t-BuNH-8,9-R,R′-nido-7,8,9-C3B8H9 (R,R′ = H,H; MeH; Me,Me; Ph,H and Ph,Ph) tricarbollide compounds. It was also used in the preparation of saturated fluoroalkyl(hydrido) complexes of Iridium.

Very strong base with weak nucleophilic character due to steric effects.

General description

Proton-sponge is also referred as 1,8-dimethylamino naphthalene. It is very strong base with weak nucleophilic character due to steric effects. It also participates in the reactions between arachno-6,9-C2B8H14 and selected acyl chlorides. It has been tested as an effective H+ scavenger.

Legal Information

Proton-sponge is a registered trademark of Sigma-Aldrich Co. LLC

Packaging

10, 50 g in glass bottle

assay99%
formsolid
InChI keyGJFNRSDCSTVPCJ-UHFFFAOYSA-N
InChI1S/C14H18N2/c1-15(2)12-9-5-7-11-8-6-10-13(14(11)12)16(3)4/h5-10H,1-4H3
mp49-51 °C (lit.)
Quality Level200
SMILES stringCN(C)c1cccc2cccc(N(C)C)c12
solubilitychloroform: soluble 50 mg/mL, clear (faint yellow to dark yellow to dark red)
Cas Number20734-58-1
This product has met the following criteria to qualify for the following awards:



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