Hoveyda-Grubbs Catalyst 2nd Generation; 97%

Code: 569755-25G D2-231

Application

It′s a phosphine free version of Grubbs 2nd Generation Catalyst with comparable reactivity, but initiates more readily at lower temperatures. Efficient...


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Your Price
€8,680.00 25G
€10,676.40 inc. VAT

Application

It′s a phosphine free version of Grubbs 2nd Generation Catalyst with comparable reactivity, but initiates more readily at lower temperatures. Efficient for metathesis of electron-deficient substrates including fluorinated olefins. Demonstrated in multiple large-scale pharmaceutical applications.It can be used as a catalyst for olefin cross-metathesis with fluorinated olefins (CM), ring-closing metathesis (RCM), ring-opening metathesis (ROM), and a sequence of a metathesis reaction and subsequent dihydroxylation of the newly formed double bond.

Legal Information

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Product of UmicoreProduct LicenseThis product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer’s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com

Other Notes

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich

Packaging

2, 10, 25 g in glass bottle

100, 500 mg in glass bottle

assay97%
formsolid
InChI keyZRPFJAPZDXQHSM-UHFFFAOYSA-L
InChI1S/C21H26N2.C10H12O.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-8(2)11-10-7-5-4-6-9(10)3;;;/h9-12H,7-8H2,1-6H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2
mp216-220 °C (lit.)
Quality Level100
reaction suitabilitycore: ruthenium, reagent type: catalystreaction type: Ring-Opening Polymerization
SMILES stringCC(C)Oc1ccccc1C=[Ru](Cl)(Cl)=C2N(CCN2c3c(C)cc(C)cc3C)c4c(C)cc(C)cc4C
storage temp.2-8°C
Cas Number301224-40-8
This product has met the following criteria to qualify for the following awards:



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