1,1-Thiocarbonyldiimidazole, >=95.0% (S)

Code: 88545-5G D2-231

Application

1,1′-Thiocarbonyldiimidazole (TCDI) is generally used as a reagent to carry out the deoxygenation of vicinal diols by forming cyclic thionocarbonate in Corey-Wint...


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Your Price
€78.90 5G
€97.05 inc. VAT

Application

1,1′-Thiocarbonyldiimidazole (TCDI) is generally used as a reagent to carry out the deoxygenation of vicinal diols by forming cyclic thionocarbonate in Corey-Winter alkene synthesis.It is used as a reagent in the enantioselective total synthesis of (+)-hapalindole Q, 12-epi-fischerindole U and welwitindolinone A.It is also used in the preparation of trithiocarbonates, xanthates, and dithiocarbamates as chain transfer agents for the reversible addition fragmentation chain transfer and macromolecular design (RAFT/ MADIX) polymerization.

Other Notes

Reagent for the synthesis of thioamides; Used in a modified Corey-Winter olefin synthesis; Preparation of thiocarbamates from alcohols which undergo radical reactions with Bu3SnH-AIBN

Packaging

1, 5, 25 g in glass bottle

assay≥95.0% (S)
formpowder
InChI keyRAFNCPHFRHZCPS-UHFFFAOYSA-N
InChI1S/C7H6N4S/c12-7(10-3-1-8-5-10)11-4-2-9-6-11/h1-6H
mp98-102 °C (lit.)
Quality Level200
reaction suitabilityreaction type: Carbonylations
SMILES stringS=C(n1ccnc1)n2ccnc2
storage temp.2-8°C
Cas Number6160-65-2
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