(S)-(+)-2-(Methoxymethyl)pyrrolidine, 99%

Code: 277053-5G D2-231

Application

Chiral auxiliary for asymmetric synthesis of propargyl alcohols and 4-nitrocyclohexanones, and for asymmetric Michael additions to enones.

(S)-(+)-...


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Your Price
€175.50 5G
Discontinued
€215.87 inc. VAT

Application

Chiral auxiliary for asymmetric synthesis of propargyl alcohols and 4-nitrocyclohexanones, and for asymmetric Michael additions to enones.

(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.

Packaging

500 mg in amber glass bottle

5 g in glass bottle

assay99%
bp62 °C/40 mmHg (lit.)
density0.933 g/mL at 25 °C (lit.)
formliquid
InChI keyCHPRFKYDQRKRRK-LURJTMIESA-N
InChI1S/C6H13NO/c1-8-5-6-3-2-4-7-6/h6-7H,2-5H2,1H3/t6-/m0/s1
optical activity[α]20/D +2.4°, c = 2 in benzene
refractive indexn20/D 1.4457 (lit.)
SMILES stringCOC[C@@H]1CCCN1
Cas Number63126-47-6
Hazard Class3
Un Number1993
Pack GroupIII
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