Methyl 3-bromobenzoate, 98%

Code: 499625-5G D2-231

General description

Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylet...


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€43.00 5G
€52.89 inc. VAT

General description

Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K4[Fe(CN)6] as a cyanating agent.

Packaging

5, 25 g in glass bottle

assay98%
bp127-128 °C/15 mmHg (lit.)
InChI keyKMFJVYMFCAIRAN-UHFFFAOYSA-N
InChI1S/C8H7BrO2/c1-11-8(10)6-3-2-4-7(9)5-6/h2-5H,1H3
mp31-33 °C (lit.)
Quality Level200
SMILES stringCOC(=O)c1cccc(Br)c1
Cas Number618-89-3
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