Diethyl (2-methylallyl)phosphonate, 97%

Code: 593095-1G D2-231

Application

Reactant for:•Enantioselective synthesis of 10-isocyano-4-cadinene and its stereoisomers with antifouling activity•Preparation of 4-Oxo-2-alkenylphospho...


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Your Price
€26.83 1G
Discontinued
€33.00 inc. VAT

Application

Reactant for:•Enantioselective synthesis of 10-isocyano-4-cadinene and its stereoisomers with antifouling activity•Preparation of 4-Oxo-2-alkenylphosphonates via silylation followed by regiospecific Friedel-Crafts acylation and isomerization

Diethyl (2-methylallyl)phosphonate can be used as a reagent in the Horner-Wadsworth-Emmons reaction to form conjugated carbon–carbon double bonds. It can also be used as a reactant for: Enantioselective total synthesis of 10-isocyano-4-cadinene as antifouling agent. Regiospecific preparation of 4-oxo-2-alkenylphosphonates (OAP) via silylation followed by Friedel-Crafts acylation and isomerization. OAP can serve as building blocks for the construction of polyethylenic chains. The synthesis of azaphosphone as a potent analgesic/anti-inflammatory agents.

General description

Diethyl (2-methylallyl)phosphonate is an organophosphorous compound. It participates in the synthesis of α-aminophosphonate derivatives and azaphosphones. The analgesic/antiinflammatory properties of these derivatives were evaluated.

Packaging

1 g in glass bottle

assay97%
bp62 °C/0.1 mmHg (lit.)
density1.013 g/mL at 25 °C (lit.)
InChI keyQOZGSMHGXZMADD-UHFFFAOYSA-N
InChI1S/C8H17O3P/c1-5-10-12(9,11-6-2)7-8(3)4/h3,5-7H2,1-2,4H3
Quality Level100
reaction suitabilityreaction type: C-C Bond Formation
refractive indexn20/D 1.4380 (lit.)
SMILES stringCCOP(=O)(CC(C)=C)OCC
Cas Number51533-70-1
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