Application

iPr-NDI is a ligand that when mixed with NiBr₂, generates an active dinuclear Ni catalyst. The catalyst has been shown to promote a variety of transformations including the cyclopropanation of alkenes and the [4+1] cycloaddition of vinylidenes and dienes.

Other Notes

Catalytic reductive [4 + 1]-cycloadditions of vinylidenes and dienesCatalytic Azoarene Synthesis from Aryl Azides Enabled by a Dinuclear Ni ComplexCatalytic Carbonylative Rearrangement of Norbornadiene via Dinuclear Carbon-Carbon Oxidative Addition