RH2(S-TCPTAD)4

Application

This dirhodium catalyst developed by the Davies lab can form C-C bonds at the most accessible tertiary C-H position with control of both regioselectivity and absolute configuration.

Other Notes

Formation of Tertiary Alcohols from the Rhodium-Catalyzed Reactions of Donor/Acceptor Carbenes with EstersHarnessing the β-Silicon Effect for Regioselective and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization by Donor/Acceptor Carbenes Derived from 1-Sulfonyl-1,2,3-triazolesSite-selective and stereoselective functionalization of non-activated tertiary C-H bonds