246-TRIS(4-METHOXYPHENYL)PYRYLIUM TET

Code: 900692-250MG D2-231

Application

2,4,6-Tris(4-methoxyphenyl)pyrylium tetrafluoroborate can be used to catalyze the stereoselective synthesis of C2-symmetric cyclobutane alkene...


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Your Price
€313.70 250MG
€385.85 inc. VAT

Application

2,4,6-Tris(4-methoxyphenyl)pyrylium tetrafluoroborate can be used to catalyze the stereoselective synthesis of C2-symmetric cyclobutane alkene dimers via photo-induced electron transfer. This method can be employed for the total synthesis of lignans such as magnosalin, endiandrin A and pellucidin A. It can also catalyze photoinduced electron transfer (PET) to initiate radical-cation Diels-Alder reactions.

Triarylpyrylium salt used as a photosensitizer in photocatalysis and polymerization. This was previously sold under catalog number S921874.

Other Notes

David Nicewicz photoredox catalysisCyclization–endoperoxidation cascade reactions of dienes mediated by a pyrylium photoredox catalystMetal-Free Ring-Opening Metathesis PolymerizationCationic Polymerization of Vinyl Ethers Controlled by Visible LightElectron-Transfer-Induced Diels ± Alder Reactions of Indole and Exocyclic Dienes: Synthesis and Quantum-Chemical Studies

Packaging

10, 250 mg in glass insert

formpowder
mp346-351 °C
Quality Level100
reaction suitabilityreagent type: catalystreaction type: Photocatalysis
SMILES stringCOC(C=C1)=CC=C1C2=[O+]C(C3=CC=C(OC)C=C3)=CC(C4=CC=C(OC)C=C4)=C2.FB(F)F.[F-]
Cas Number580-34-7
This product has met the following criteria to qualify for the following awards:



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