Application
2,4,6-Tris(4-methoxyphenyl)pyrylium tetrafluoroborate can be used to catalyze the stereoselective synthesis of C2-symmetric cyclobutane alkene dimers via photo-induced electron transfer. This method can be employed for the total synthesis of lignans such as magnosalin, endiandrin A and pellucidin A. It can also catalyze photoinduced electron transfer (PET) to initiate radical-cation Diels-Alder reactions.
Triarylpyrylium salt used as a photosensitizer in photocatalysis and polymerization. This was previously sold under catalog number S921874.
Other Notes
David Nicewicz photoredox catalysisCyclization–endoperoxidation cascade reactions of dienes mediated by a pyrylium photoredox catalystMetal-Free Ring-Opening Metathesis PolymerizationCationic Polymerization of Vinyl Ethers Controlled by Visible LightElectron-Transfer-Induced Diels ± Alder Reactions of Indole and Exocyclic Dienes: Synthesis and Quantum-Chemical Studies
Packaging
10, 250 mg in glass insert
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