MANGANESE(IV) OXIDE (PRECIPITATED ACTIVE

Code: 8059580100 D2-231

Analysis Note

Assay (iodometric, calc. on dried substance): ≥ 90.0 %Loss on drying: ≤ 3.5 %Oxidation Activity: passes test

Application

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€41.90 EACH
€51.54 inc. VAT

Analysis Note

Assay (iodometric, calc. on dried substance): ≥ 90.0 %Loss on drying: ≤ 3.5 %Oxidation Activity: passes test

Application

Manganese(IV) oxide (MnO2) can be used as an oxidizing agent for the oxidation of: Allylic alcohols to α, β-ethylenic aldehydes, or ketones. Propargylic alcohols to alkynic aldehydes or ketones. Benzylic and heterocyclic alcohols to conjugated aromatic aldehydes or ketones. Amines to aldehydes, imines, amides, and diazo compounds. Methyl arenes to form primary amides in the presence of urea and oxygen. MnO2 can also be used to synthesize disubstituted oxazolines from aldoximes via in situ nitrile oxide formation. Non-activated cyclic and acyclic alcohols oxidized to ketone analogs using stoichiometric MnO2 and a ruthenium catalyst.

Packaging

1 kg in Plastic bottle

bulk density600‑800 kg/m3
density5.21 g/cm3 at 21 °C
formpowder
InChI keyNUJOXMJBOLGQSY-UHFFFAOYSA-N
InChI1S/Mn.2O
potency>3478 mg/kg LD50, oral (Rat)
Quality Level200
reaction suitabilityreagent type: oxidant
solubilityinsoluble ﹤0.001 g/L
storage temp.2-30°C
Code
Description
Unit Size
List Price
Qty
8059581000
Unit:EACH
List Price: €86.10
Source:List Price
ADD
Cas Number1313-13-9
This product has met the following criteria: