DAVEPHOS-PD-G3

Code: 804959-250MG D2-231

Application

Pd precatalyst for cross-coupling

General description

DavePhos-Pd-G3 is a modified G3 precatalyst (G3′). It has been synthesized by B...


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€132.00 250MG
€162.36 inc. VAT
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Application

Pd precatalyst for cross-coupling

General description

DavePhos-Pd-G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solutions and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

Packaging

1, 5 g in glass bottle

250 mg in glass bottle

assay95%
featuregeneration 3
formsolid
functional groupphosphine
impurities﹤5% THF
InChI keyFBIRGVXUSGLNQE-UHFFFAOYSA-M
InChI1S/C26H36NP.C12H10N.CH4O3S.Pd/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-12,17-22H,3-8,13-16H2,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
mp183-200 °C (decomp)
Quality Level100
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: ligand, reagent type: catalystreaction type: Cross Couplings
SMILES stringCN(C)C1=C(C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2)C=CC=C1.NC5=C(C6=C([Pd]OS(C)(=O)=O)C=CC=C6)C=CC=C5
Cas Number1445085-87-9
This product has met the following criteria to qualify for the following awards:



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