ALPHOS

Code: 799718-100MG D2-231

Application

AlPhos is a biaryl monophosphine ligand that can be used: In the Pd-catalyzed Buchwald-Hartwig cross-coupling reactions. To synthesize highly regioselective aryl ...


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€144.77 100MG
€178.07 inc. VAT
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Application

AlPhos is a biaryl monophosphine ligand that can be used: In the Pd-catalyzed Buchwald-Hartwig cross-coupling reactions. To synthesize highly regioselective aryl fluorides by Pd-catalyzed fluorination of a variety of activated aryl and heteroaryl triflates and bromides. To prepare aryl thioethers by C–S cross-coupling of thiols with aromatic electrophile in the presence of palladium catalyst.

Packaging

100 mg in glass bottle

assay≥95%
formpowder
functional groupphosphine
InChI keyALWIRDZSIXWCBO-VABCSHEKSA-N
InChI1S/C52H67F4OP/c1-9-10-12-38-46(53)48(55)45(49(56)47(38)54)44-40(29(4)5)21-39(28(2)3)43(42(44)30(6)7)37-13-11-14-41(57-8)50(37)58(51-22-31-15-32(23-51)17-33(16-31)24-51)52-25-34-18-35(26-52)20-36(19-34)27-52/h11,13-14,21,28-36H,9-10,12,15-20,22-27H2,1-8H3/t31-,32+,33?,34-,35+,36?,51+,52?,58?
mp218-223 °C
Quality Level100
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: ligandreaction type: Cross Couplings
storage temp.−20°C
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