tert-Butoxy bis(dimethylamino)methane,

Code: 384216-10G D2-231

Application

Reactant for: Preparation of pyrroloquinazolines as photochemotherapeutic agents Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereosele...


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Your Price
€233.00 10G
€286.59 inc. VAT

Application

Reactant for: Preparation of pyrroloquinazolines as photochemotherapeutic agents Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction Aminomethylenation reactions

tert-Butoxy bis(dimethylamino)methane (Bredereck′s reagent) may be used in the following studies:Enamination of active methylene and methyl groups. As condensation reagent in the synthesis of benz[c,d]indoles.Preparation of methyl and ethyl 3-dimethylamino-2-(indol-3-yl)propenoate.Synthesis of the macrolide natural product (-)-gloeosporone.Preparation of new bioactive naphthyridine alkaloids lophocladine A and B.Preparation of (E/Z)-ethyl 6,7-dichloro-3-[1-cyano-2-(dimethylamino)vinyl]-1-methyl-1H-indole-2-carboxylate.Preparation of (E)-ethyl 3-(dimethylamino)-2-(1H-indol-3-yl)acrylate.α-Enamination of ketones and esters.

Packaging

1, 10 g in glass bottle

bp50-55 °C/15 mmHg (lit.)
density0.844 g/mL at 25 °C (lit.)
formliquid
InChI keyHXRAMSFGUAOAJR-UHFFFAOYSA-N
InChI1S/C9H22N2O/c1-9(2,3)12-8(10(4)5)11(6)7/h8H,1-7H3
Quality Level200
refractive indexn20/D 1.422 (lit.)
SMILES stringCN(C)C(OC(C)(C)C)N(C)C
Cas Number5815-08-7
Hazard Class3
Un Number1993
Pack GroupIII
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