Dichlorobis(tri-o-tolylphosphine)palladium(II), 97%

Code: 453048-5G D2-231

Application

Application Guide for Palladium Catalyzed Cross-Coupling ReactionsCatalyst for C-C and C-N coupling reaction.

Dichlorobis(tri-o-tolylphosphine)pall...


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Application

Application Guide for Palladium Catalyzed Cross-Coupling ReactionsCatalyst for C-C and C-N coupling reaction.

Dichlorobis(tri-o-tolylphosphine)palladium(II) has been employed as catalyst for the following studies:Reaction of tributyltin enolates, prepared in situ from tributyltin methoxide and enol acetates, with aryl bromides.Coupling reaction of aryl bromides with vinylic acetates.Negishi-Reformatsky coupling reaction of aryl bromides with ethyl 2-(tributylstannyl)acetates.Synthesis of (E)-methyl 3-(7-indolyl)-2-methacrylate, via Heck reaction.Synthesis of imidazopyrimidine derivatives.

General description

Dichlorobis(tri-o-tolylphosphine)palladium(II) is a useful catalyst for C-C and C-N coupling reactions.

Packaging

1, 5 g in glass bottle

assay97%
formsolid
InChI keyOTYPIDNRISCWQY-UHFFFAOYSA-L
InChI1S/2C21H21P.2ClH.Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;;/h2*4-15H,1-3H3;2*1H;/q;;;;+2/p-2
mp280 °C (dec.) (lit.)
Quality Level200
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalystcore: palladium
SMILES stringCl[Pd]Cl.Cc1ccccc1P(c2ccccc2C)c3ccccc3C.Cc4ccccc4P(c5ccccc5C)c6ccccc6C
Cas Number40691-33-6
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