3-PROPYL-3-(2356-TETRAFLUORO-4-NITRO

Code: 809136-250MG D2-231

Application

This compound undergoes cycloreversion to form the fluoro(hetero)aryl ketene, which undergoes efficient coupling with nucleophiles and allows rapid incorporation ...


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Your Price
€41.25 250MG
Discontinued
€50.74 inc. VAT

Application

This compound undergoes cycloreversion to form the fluoro(hetero)aryl ketene, which undergoes efficient coupling with nucleophiles and allows rapid incorporation of highly fluorinated α-fluoro(hetero)aryl acetic acid derivatives.

General description

3-Propyl-3-(2,3,5,6-tetrafluoro-4-nitrophenyl)-1,5-dioxaspiro[5.5]undecane-2,4-dione can be synthesized from pentafluoronitrobenzene, 3-propyl-1,5-dioxaspiro[5.5]undecane-2,4-dione, N,N-diisopropylethylamine and CH3CN.

Other Notes

Selective Perfluoro- and Polyfluoroarylation of Meldrum’;s Acid

Packaging

250 mg in glass bottle

formpowder
InChI keyJWAHHCQJIGIGMQ-UHFFFAOYSA-N
InChI1S/C18H17F4NO6/c1-2-6-18(9-10(19)12(21)14(23(26)27)13(22)11(9)20)15(24)28-17(29-16(18)25)7-4-3-5-8-17/h2-8H2,1H3
Quality Level100
SMILES stringFC1=C(F)C([N+]([O-])=O)=C(F)C(F)=C1C2(CCC)C(OC3(CCCCC3)OC2=O)=O
storage temp.2-8°C
Cas Number1632145-40-4
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