2-(TRIMETHYLSILYL)-2-CYCLOHEXEN-1-

Code: 805041-500MG D2-231

Application

The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduc...


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€141.82 500MG
€174.44 inc. VAT
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Application

The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.

General description

2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.

Other Notes

Cycloadditions of Cyclohexynes and Cyclopentyne

Modular synthesis of the pentacyclic core of batrachotoxin and select batrachotoxin analogue designs

Packaging

500 mg in glass bottle

density0.8680 g/mL at 25 °C
descriptionFp: 15.8°F
formliquid
InChI keySXGCQSJRVVKTOH-UHFFFAOYSA-N
InChI1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3
Quality Level100
refractive indexn20/D 1.4524
SMILES stringO=C1C([Si](C)(C)C)=CCCC1
storage temp.−20°C
Cas Number72162-99-3
Hazard Class4.1
Un Number1325
Pack GroupIII
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