Application
The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.
Legal Information
Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.
Other Notes
Technology Spotlight: Jamison Nickel (II) Precatalysts A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes
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