(-)-DIP-Chloride,

Code: 317020-5G D2-231

Application

Reagent used for an enantioselective reduction of (chloroacetyl) benzofurans to chlorohydrins which serve as intermediates for the corresponding epoxides and amin...


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€82.60 5G
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OVERVIEW

Application

Reagent used for an enantioselective reduction of (chloroacetyl) benzofurans to chlorohydrins which serve as intermediates for the corresponding epoxides and aminoalcohols. For a short paper on the preparation of DIP halides and their use in stereoselective reductions see Chem. Commun. 1053 (1994).

Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.

Legal Information

DIP-Chloride is a trademark of Sigma-Aldrich Co. LLC

Packaging

5, 25, 100 g in glass bottle

SPECIFICATIONS
formsolid
InChI keyPSEHHVRCDVOTID-VMAIWCPRSA-N
InChI1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13+,14+,15-,16-,17-,18-/m1/s1
mp52-56 °C (lit.)
Quality Level100
SMILES stringC[C@H]1[C@@H](CC2CCC1C2(C)C)B(Cl)[C@@H]3CC4CCC([C@H]3C)C4(C)C
DOCUMENTS
RANGE
ATTRIBUTES
Cas Number85116-37-6
Hazard Class8
Un Number3261
Pack GroupII
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